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| 06.01.2011 | RCD Espanyol | 1-1 | Atlético Madrid | |
| 22.12.2010 | Atlético Madrid | 1-0 | RCD Espanyol |
| 05.01.2011 | Deportivo La Coruña | 3-1 AET | Córdoba CF | |
| 21.12.2010 | Córdoba CF | 1-1 | Deportivo La Coruña |
| 05.01.2011 | Athletic Bilbao | 1-1 | FC Barcelona | |
| 21.12.2010 | FC Barcelona | 0-0 | Athletic Bilbao |
| 05.01.2011 | Málaga CF | 0-3 | Sevilla FC | |
| 22.12.2010 | Sevilla FC | 5-3 | Málaga CF |
| 06.01.2011 | Getafe CF | 1-3 | Real Betis | |
| 22.12.2010 | Real Betis | 1-2 | Getafe CF |
| 06.01.2011 | Levante UD | 2-0 | Real Madrid | |
| 22.12.2010 | Real Madrid | 8-0 | Levante UD |
| 06.01.2011 | Real Mallorca | 3-4 | UD Almería | |
| 22.12.2010 | UD Almería | 4-3 | Real Mallorca |
| 06.01.2011 | Villarreal CF | 4-2 | Valencia CF | |
| 21.12.2010 | Valencia CF | 0-0 | Villarreal CF |
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