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GMT 01:00
| 31.10.2007 | |||
| 18:00 | Shakhtar Donetsk | 4-1 | Arsenal Kyiv |
| 17:30 | Desna Chernihiv | 1-1/p.2-4 | Naftovyk-Ukrnafta |
| 17:00 | Chernomorets Odessa | 2-2/p.3-1 | Metalist Kharkiv |
| 16:00 | Stal Alchevsk | 1-2 | Metalurg Donetsk |
| 13:00 | Dinamo Simferopol | 1-4 | Dynamo Kyiv |
| 13:00 | FC Lviv | 1-2 | Illichivets |
| 13:00 | Nyva Ternopil | 0-0/p.5-6 | Tavriya Simferopol |
| 12:30 | Dniester Ovidiopol | 0-1 | Vorskla |
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