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Spain| 06.05.2021 | EUL | Arsenal FC | 0-0 | Villarreal CF | |
| 29.04.2021 | EUL | Villarreal CF | 2-1 | Arsenal FC | |
| 15.04.2009 | CL | Arsenal FC | 3-0 | Villarreal CF | |
| 07.04.2009 | CL | Villarreal CF | 1-1 | Arsenal FC | |
| 25.04.2006 | CL | Villarreal CF | 0-0 | Arsenal FC | |
| 19.04.2006 | CL | Arsenal FC | 1-0 | Villarreal CF |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 4 | 1 | 1 | 13 | 5 | 8 |
| away | 6 | 2 | 3 | 1 | 11 | 5 | 6 |
| total | 6 | 3 | 3 | 0 | 14 | 6 | 8 |
| Arsenal FC win | 33.33% | 2 |
| draw | 50.00% | 3 |
| Arsenal FC lose | 16.67% | 1 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 3 | 1 | 12 | 5 | 7 |
| away | 6 | 3 | 1 | 2 | 6 | 5 | 1 |
| total | 6 | 2 | 2 | 2 | 5 | 5 | 0 |
| Villarreal win | 16.67% | 1 |
| draw | 50.00% | 3 |
| Villarreal lose | 33.33% | 2 |
| 05.04.2025 | PR | Everton | 1-1 | Arsenal FC |  |
| 01.04.2025 | PR | Arsenal FC | 2-1 | Fulham |  |
| 16.03.2025 | PR | Arsenal FC | 1-0 | Chelsea FC | |
| 12.03.2025 | CL | Arsenal FC | 2-2 | PSV Eindhoven | |
| 09.03.2025 | PR | Manchester United | 1-1 | Arsenal FC | |
| 04.03.2025 | CL | PSV Eindhoven | 1-7 | Arsenal FC | |
| 06.04.2025 | D1 | Villarreal CF | 0-0 | Athletic Bilbao | |
| 30.03.2025 | D1 | Getafe CF | 1-2 | Villarreal CF | |
| 15.03.2025 | D1 | Villarreal CF | 1-2 | Real Madrid |  |
| 08.03.2025 | D1 | Deportivo Alavés | 1-0 | Villarreal CF | |
| 22.02.2025 | D1 | Rayo Vallecano | 0-1 | Villarreal CF | |
| 15.02.2025 | D1 | Villarreal CF | 1-1 | Valencia CF | |
| over 2.5 | 44.68% | 21 |
| under 2.5 | 55.32% | 26 |
| over 2.5 | 61.29% | 19 |
| under 2.5 | 38.71% | 12 |
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