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Spain| 06.05.2021 | EUL | Arsenal FC | 0-0 | Villarreal CF | |
| 29.04.2021 | EUL | Villarreal CF | 2-1 | Arsenal FC | |
| 15.04.2009 | CL | Arsenal FC | 3-0 | Villarreal CF | |
| 07.04.2009 | CL | Villarreal CF | 1-1 | Arsenal FC | |
| 25.04.2006 | CL | Villarreal CF | 0-0 | Arsenal FC | |
| 19.04.2006 | CL | Arsenal FC | 1-0 | Villarreal CF |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 5 | 1 | 0 | 17 | 6 | 11 |
| away | 6 | 2 | 2 | 2 | 6 | 5 | 1 |
| total | 6 | 3 | 1 | 2 | 9 | 6 | 3 |
| Arsenal FC win | 33.33% | 2 |
| draw | 50.00% | 3 |
| Arsenal FC lose | 16.67% | 1 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 2 | 2 | 12 | 14 | -2 |
| away | 6 | 4 | 1 | 1 | 13 | 7 | 6 |
| total | 6 | 4 | 1 | 1 | 14 | 7 | 7 |
| Villarreal win | 16.67% | 1 |
| draw | 50.00% | 3 |
| Villarreal lose | 33.33% | 2 |
| 02.11.2024 | PR | Newcastle United | 1-0 | Arsenal FC |  |
| 30.10.2024 | LC | Preston NE | 0-3 | Arsenal FC |  |
| 27.10.2024 | PR | Arsenal FC | 2-2 | Liverpool |  |
| 22.10.2024 | CL | Arsenal FC | 1-0 | Shakhtar Donetsk | |
| 19.10.2024 | PR | Bournemouth | 2-0 | Arsenal FC | |
| 05.10.2024 | PR | Arsenal FC | 3-1 | Southampton | |
| 02.11.2024 | D1 | Villarreal CF | P-P | Rayo Vallecano |  |
| 29.10.2024 | Cup | UD Poblense | 1-6 | Villarreal CF | |
| 26.10.2024 | D1 | Real Valladolid | 1-2 | Villarreal CF | |
| 20.10.2024 | D1 | Villarreal CF | 1-1 | Getafe CF | |
| 05.10.2024 | D1 | Real Madrid | 2-0 | Villarreal CF | |
| 30.09.2024 | D1 | Villarreal CF | 3-1 | UD Las Palmas | |
| over 2.5 | 45.00% | 9 |
| under 2.5 | 55.00% | 11 |
| over 2.5 | 77.78% | 14 |
| under 2.5 | 22.22% | 4 |
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