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| 25.08.2024 | D3 | FC Barcelona B | 1-1 | Real Unión | |
| 03.03.2024 | D3 | Real Unión | 0-0 | FC Barcelona B | |
| 03.09.2023 | D3 | FC Barcelona B | 2-1 | Real Unión | |
| 18.03.2023 | D3 | Real Unión | 0-1 | FC Barcelona B | |
| 17.12.2022 | D3 | FC Barcelona B | 2-1 | Real Unión | |
| 05.05.2002 | D3-2 | Real Unión | 3-2 | Barcelona B |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 1 | 3 | 11 | 7 | 4 |
| away | 6 | 2 | 0 | 4 | 5 | 15 | -10 |
| total | 6 | 3 | 0 | 3 | 9 | 6 | 3 |
| Real Union win | 14.28% | 1 |
| draw | 42.86% | 3 |
| Real Union lose | 42.86% | 3 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 0 | 4 | 2 | 6 | 11 | -5 |
| away | 6 | 2 | 2 | 2 | 7 | 9 | -2 |
| total | 6 | 1 | 3 | 2 | 6 | 11 | -5 |
| Barcelona B win | 42.85% | 3 |
| draw | 42.86% | 3 |
| Barcelona B lose | 14.29% | 1 |
| 02.02.2025 | D3 | Barakaldo CF | 0-2 | Real Unión |  |
| 25.01.2025 | D3 | Real Unión | 5-0 | Gimn. Segoviana | |
| 17.01.2025 | D3 | Sestao River | 0-1 | Real Unión | |
| 12.01.2025 | D3 | Real Unión | 1-2 | Zamora CF |  |
| 22.12.2024 | D3 | Real Unión | 0-1 | Cultural Leonesa | |
| 14.12.2024 | D3 | CD Arenteiro | 3-0 | Real Unión | |
| 01.02.2025 | D3 | Real Sociedad B | 3-0 | FC Barcelona B | |
| 25.01.2025 | D3 | Ourense CF | 1-1 | FC Barcelona B |  |
| 19.01.2025 | D3 | FC Barcelona B | 0-3 | SD Ponferradina | |
| 11.01.2025 | D3 | Cultural Leonesa | 1-1 | FC Barcelona B | |
| 22.12.2024 | D3 | FC Barcelona B | 2-2 | Athletic Bilbao B | |
| 13.12.2024 | D3 | CA Osasuna B | 1-2 | FC Barcelona B | |
| over 2.5 | 54.55% | 12 |
| under 2.5 | 45.45% | 10 |
| over 2.5 | 59.09% | 13 |
| under 2.5 | 40.91% | 9 |
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