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| 25.08.2024 | D3 | FC Barcelona B | 1-1 | Real Unión | |
| 03.03.2024 | D3 | Real Unión | 0-0 | FC Barcelona B | |
| 03.09.2023 | D3 | FC Barcelona B | 2-1 | Real Unión | |
| 18.03.2023 | D3 | Real Unión | 0-1 | FC Barcelona B | |
| 17.12.2022 | D3 | FC Barcelona B | 2-1 | Real Unión | |
| 05.05.2002 | D3-2 | Real Unión | 3-2 | Barcelona B |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 4 | 1 | 1 | 12 | 3 | 9 |
| away | 6 | 1 | 1 | 4 | 5 | 8 | -3 |
| total | 6 | 2 | 2 | 2 | 6 | 5 | 1 |
| Real Union win | 14.28% | 1 |
| draw | 42.86% | 3 |
| Real Union lose | 42.86% | 3 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 2 | 2 | 9 | 8 | 1 |
| away | 6 | 0 | 1 | 5 | 5 | 17 | -12 |
| total | 6 | 2 | 2 | 2 | 8 | 11 | -3 |
| Barcelona B win | 42.85% | 3 |
| draw | 42.86% | 3 |
| Barcelona B lose | 14.29% | 1 |
| 13.04.2025 | D3 | Real Unión | 3-0 | CD Lugo |  |
| 06.04.2025 | D3 | SD Ponferradina | 3-1 | Real Unión |  |
| 28.03.2025 | D3 | Real Unión | 0-0 | FC Andorra |  |
| 22.03.2025 | D3 | Cultural Leonesa | 1-1 | Real Unión | |
| 16.03.2025 | D3 | Ourense CF | 1-0 | Real Unión | |
| 09.03.2025 | D3 | Real Unión | 1-0 | CD Arenteiro | |
| 13.04.2025 | D3 | FC Barcelona B | 2-0 | Sestao River | |
| 04.04.2025 | D3 | Celta Vigo Fortuna | 3-1 | FC Barcelona B | |
| 29.03.2025 | D3 | FC Barcelona B | 2-0 | Cultural Leonesa | |
| 21.03.2025 | D3 | Athletic Bilbao B | 2-2 | FC Barcelona B | |
| 19.03.2025 | CF | RCD Espanyol | 5-0 | FC Barcelona B | |
| 15.03.2025 | D3 | FC Barcelona B | 1-1 | SD Tarazona | |
| over 2.5 | 50.00% | 16 |
| under 2.5 | 50.00% | 16 |
| over 2.5 | 57.58% | 19 |
| under 2.5 | 42.42% | 14 |
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