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England| 03.05.2022 | CL | Villarreal CF | 2-3 | Liverpool | |
| 27.04.2022 | CL | Liverpool | 2-0 | Villarreal CF | |
| 05.05.2016 | EUL | Liverpool | 3-0 | Villarreal CF | |
| 28.04.2016 | EUL | Villarreal CF | 1-0 | Liverpool | |
| 30.07.2008 | CF | Villarreal CF | 0-0 | Liverpool |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 3 | 1 | 14 | 7 | 7 |
| away | 6 | 2 | 1 | 3 | 8 | 8 | 0 |
| total | 6 | 3 | 2 | 1 | 13 | 5 | 8 |
| Villarreal win | 20.00% | 1 |
| draw | 20.00% | 1 |
| Villarreal lose | 60.00% | 3 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 5 | 1 | 0 | 19 | 5 | 14 |
| away | 6 | 2 | 2 | 2 | 9 | 7 | 2 |
| total | 6 | 3 | 1 | 2 | 14 | 7 | 7 |
| Liverpool win | 60.00% | 3 |
| draw | 20.00% | 1 |
| Liverpool lose | 20.00% | 1 |
| 15.02.2025 | D1 | Villarreal CF | 1-1 | Valencia CF |  |
| 08.02.2025 | D1 | UD Las Palmas | 1-2 | Villarreal CF |  |
| 01.02.2025 | D1 | Villarreal CF | 5-1 | Real Valladolid | |
| 25.01.2025 | D1 | Atlético Madrid | 1-1 | Villarreal CF | |
| 20.01.2025 | D1 | Villarreal CF | 4-0 | Real Mallorca | |
| 13.01.2025 | D1 | Real Sociedad | 1-0 | Villarreal CF |  |
| over 2.5 | 65.38% | 17 |
| under 2.5 | 34.62% | 9 |
| over 2.5 | 61.54% | 24 |
| under 2.5 | 38.46% | 15 |
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