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Italy| 17.12.2022 | CF | SSC Napoli | 2-3 | Villarreal CF | |
| 25.02.2016 | EUL | SSC Napoli | 1-1 | Villarreal CF | |
| 18.02.2016 | EUL | Villarreal CF | 1-0 | SSC Napoli | |
| 07.12.2011 | CL | Villarreal CF | 0-2 | SSC Napoli | |
| 27.09.2011 | CL | SSC Napoli | 2-0 | Villarreal CF | |
| 24.02.2011 | EUL | Villarreal CF | 2-1 | SSC Napoli |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 3 | 1 | 12 | 6 | 6 |
| away | 6 | 1 | 2 | 3 | 8 | 9 | -1 |
| total | 6 | 2 | 2 | 2 | 12 | 7 | 5 |
| Villarreal win | 42.86% | 3 |
| draw | 28.57% | 2 |
| Villarreal lose | 28.57% | 2 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 4 | 0 | 2 | 6 | 5 | 1 |
| away | 6 | 5 | 0 | 1 | 13 | 7 | 6 |
| total | 6 | 6 | 0 | 0 | 13 | 4 | 9 |
| Napoli win | 28.57% | 2 |
| draw | 28.57% | 2 |
| Napoli lose | 42.86% | 3 |
| 25.01.2025 | D1 | Atlético Madrid | 1-1 | Villarreal CF |  |
| 20.01.2025 | D1 | Villarreal CF | 4-0 | Real Mallorca |  |
| 13.01.2025 | D1 | Real Sociedad | 1-0 | Villarreal CF |  |
| 22.12.2024 | D1 | CD Leganés | 2-5 | Villarreal CF | |
| 18.12.2024 | D1 | Villarreal CF | 1-1 | Rayo Vallecano | |
| 15.12.2024 | D1 | Villarreal CF | 1-2 | Real Betis | |
| 25.01.2025 | D1 | SSC Napoli | 2-1 | Juventus FC | |
| 18.01.2025 | D1 | Atalanta Bergamo | 2-3 | SSC Napoli | |
| 12.01.2025 | D1 | SSC Napoli | 2-0 | Hellas Verona | |
| 04.01.2025 | D1 | Fiorentina | 0-3 | SSC Napoli | |
| 29.12.2024 | D1 | SSC Napoli | 1-0 | Venezia FC | |
| 21.12.2024 | D1 | Genoa | 1-2 | SSC Napoli | |
| over 2.5 | 65.22% | 15 |
| under 2.5 | 34.78% | 8 |
| over 2.5 | 52.00% | 13 |
| under 2.5 | 48.00% | 12 |
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