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| 12.01.2025 | D3 | Real Unión | 1-2 | Zamora CF | |
| 10.04.2022 | D3 | Zamora CF | 0-1 | Real Unión | |
| 27.11.2021 | D3 | Real Unión | 2-0 | Zamora CF | |
| 18.02.2012 | D3-2 | Real Unión | 1-1 | Zamora CF | |
| 25.09.2011 | D3-2 | Zamora CF | 3-1 | Real Unión | |
| 27.02.2011 | D3-2 | Zamora CF | 1-0 | Real Unión |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 4 | 1 | 1 | 6 | 4 | 2 |
| away | 6 | 1 | 2 | 3 | 4 | 6 | -2 |
| total | 6 | 3 | 2 | 1 | 6 | 4 | 2 |
| Zamora ESP win | 35.72% | 5 |
| draw | 35.71% | 5 |
| Zamora ESP lose | 28.57% | 4 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 3 | 1 | 2 | 10 | 5 | 5 |
| away | 6 | 1 | 1 | 4 | 5 | 8 | -3 |
| total | 6 | 1 | 2 | 3 | 3 | 6 | -3 |
| Real Union win | 28.58% | 4 |
| draw | 35.71% | 5 |
| Real Union lose | 35.71% | 5 |
| 06.04.2025 | D3 | Ourense CF | 1-0 | Zamora CF |  |
| 30.03.2025 | D3 | Zamora CF | 1-0 | Unionistas Salamanca |  |
| 22.03.2025 | D3 | Zamora CF | 1-1 | Gimnàstic Tarragona |  |
| 15.03.2025 | D3 | Real Sociedad B | 0-1 | Zamora CF | |
| 09.03.2025 | D3 | Cultural Leonesa | 1-1 | Zamora CF | |
| 02.03.2025 | D3 | Zamora CF | 2-1 | Barakaldo CF | |
| 06.04.2025 | D3 | SD Ponferradina | 3-1 | Real Unión | |
| 28.03.2025 | D3 | Real Unión | 0-0 | FC Andorra | |
| 22.03.2025 | D3 | Cultural Leonesa | 1-1 | Real Unión | |
| 16.03.2025 | D3 | Ourense CF | 1-0 | Real Unión | |
| 09.03.2025 | D3 | Real Unión | 1-0 | CD Arenteiro | |
| 01.03.2025 | D3 | SD Amorebieta | 1-0 | Real Unión | |
| over 2.5 | 27.03% | 10 |
| under 2.5 | 72.97% | 27 |
| over 2.5 | 48.39% | 15 |
| under 2.5 | 51.61% | 16 |
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