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| 12.01.2025 | D3 | Real Unión | 1-2 | Zamora CF | |
| 10.04.2022 | D3 | Zamora CF | 0-1 | Real Unión | |
| 27.11.2021 | D3 | Real Unión | 2-0 | Zamora CF | |
| 18.02.2012 | D3-2 | Real Unión | 1-1 | Zamora CF | |
| 25.09.2011 | D3-2 | Zamora CF | 3-1 | Real Unión | |
| 27.02.2011 | D3-2 | Zamora CF | 1-0 | Real Unión |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 3 | 2 | 1 | 7 | 3 | 4 |
| away | 6 | 1 | 2 | 3 | 5 | 8 | -3 |
| total | 6 | 3 | 0 | 3 | 6 | 5 | 1 |
| Zamora ESP win | 35.72% | 5 |
| draw | 35.71% | 5 |
| Zamora ESP lose | 28.57% | 4 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 1 | 3 | 11 | 7 | 4 |
| away | 6 | 2 | 0 | 4 | 5 | 15 | -10 |
| total | 6 | 3 | 0 | 3 | 9 | 6 | 3 |
| Real Union win | 28.58% | 4 |
| draw | 35.71% | 5 |
| Real Union lose | 35.71% | 5 |
| 01.02.2025 | D3 | Zamora CF | 0-2 | Athletic Bilbao B |  |
| 26.01.2025 | D3 | SD Tarazona | 1-0 | Zamora CF | |
| 19.01.2025 | D3 | Zamora CF | 1-0 | CA Osasuna B |  |
| 12.01.2025 | D3 | Real Unión | 1-2 | Zamora CF | |
| 22.12.2024 | D3 | Zamora CF | 3-0 | CD Arenteiro | |
| 14.12.2024 | D3 | Gimnàstic Tarragona | 1-0 | Zamora CF | |
| 02.02.2025 | D3 | Barakaldo CF | 0-2 | Real Unión | |
| 25.01.2025 | D3 | Real Unión | 5-0 | Gimn. Segoviana | |
| 17.01.2025 | D3 | Sestao River | 0-1 | Real Unión | |
| 12.01.2025 | D3 | Real Unión | 1-2 | Zamora CF | |
| 22.12.2024 | D3 | Real Unión | 0-1 | Cultural Leonesa | |
| 14.12.2024 | D3 | CD Arenteiro | 3-0 | Real Unión | |
| over 2.5 | 28.57% | 8 |
| under 2.5 | 71.43% | 20 |
| over 2.5 | 54.55% | 12 |
| under 2.5 | 45.45% | 10 |
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